HPLC Columns

TSKgel SuperMultiporeHZ-M

The TSKgel SuperMultiporeHZ-M column is packed with 4 µm cross-linked poly(styrene/divinylbenzene) particles containing a wide range of pore sizes. The multi-pore particle synthesis technology essentially creates a linear calibration curve within each particle, thereby greatly diminishing chromatograms with inflection points. This base material, coupled with the semi-micro column dimensions (4.6 mm ID × 15 cm), offers users high speed and low solvent consumption analyses with precise results. 

The TSKgel SuperMultiporeHZ-M column is for the analysis of organic-soluble polymers with molecular weights from 500 to 1 × 106 Da, providing high speed and high resolution analysis with lowered solvent consumption. The columns are shipped in THF, which cannot be replaced for any other organic solvent.


P/NDescriptionParticle Size Housing MaterialID (mm)Length (cm)Price ($) 
0021488TSKgel SuperMultiporeHZ-M4Stainless Steel4.6152,422

Product Attributes

Base Material: polystyrene-divinylbenzene
Particle size (mean): 4 µm*
Pore size (mean): 14 nm
Exclusion limit (PST/THF): 2.0 × 10Da
Separation range: 500 ~ 1.0 × 10Da
Theoretical plates/15cm column: 16,000

*Particle size distribution is monodisperse.

Polystyrene Calibration Curves


Columns: TSKgel SuperMultiporeHZ-N,
3 µm, 4.6 mm ID × 15 cm
TSKgel SuperMultiporeHZ-M,
4 µm, 4.6 mm ID × 15 cm
TSKgel SuperMultiporeHZ-H,
6 µm, 4.6 mm ID × 15 cm

Mobile phase: THF
Flow rate: 0.35 mL/min
Detection: UV @ 254 nm
Temperature: 25 °C
Samples: PStQuick polystyrene standards


Comparison for Separation of Acrylic Resin


Column: A. TSKgel SuperMultiporeHZ-M,
4.6 mm ID × 15 cm × 4
B. TSKgel SuperHZ4000 + 3000 + 2500 + 2000,
4.6 mm ID × 15 cm × 1

Mobile phase: THF
Detection: RI
Temperature: 40 °C
Injection vol.: 10 μL
Samples: acrylic resin


Separation of Various Polymers




Column: TSKgel SuperMultiporeHZ-M,
 4 μm, 4.6 mm ID × 15 cm × 4

Mobile phase: THF
Flow rate: 0.35 mL/min
Detection: RI
Injection vol.:
25 °C
10 μL
Sample conc.: 0.3%

For additional applications, please see our applications database.


Code #DescriptionLiterature Type
AN018 Semi-micro Columns for Size-Exclusion Chromatography in Organic Solvent Systems:TSKgel SuperMultiporeHZ Series Columns Application Note
AN026 Which GPC Column First?Application Note
AN029 Reduce Oligosaccharide Analysis Time with TSKgel SuperOligoPW Size Exclusion Chromatography Columns Packed with Three Micron ParticlesApplication Note
AN042 An Approach to Failure Analysis of PC/ABS Resins Used in Automobile Parts: Molar Mass Determination via Gel Permeation ChromatographyApplication Note
AN043 Molar Mass Determination of a Synthetic Rubber Resin via Single-, Dual- and Triple-Detector Gel Permeation ChromatographyApplication Note
AN079 Monitoring Single-chain Nanoparticle Formation and Characterization of Nanoparticles using the EcoSEC GPC SystemApplication Note
DS1229 TSKgel SuperMultiporeHZ ProductsOperating Conditions and Specifications
IM01 TSKgel Column Instruction ManualInstruction Manual
LCAT01D TSKgel U/HPLC Columns 2019 Product Guide -- SEC, H Series ColumnsProduct Catalog
PD08 Simple, Fast and High Throughput Copolymer Analysis Using the EcoSEC GPC SystemPerformance Data
PO20 TSKgel SuperMultiporeHZ ColumnsProduct Overview
SR105 Semi-micro for Size Exclusion Chromatography in Organic Solvent Systems: TSKgel SuperMultiporeHZ SeriesSeparation Report
TP108 Characteristics of newly developed, monodisperse multi-pore organic GPC columnsTechnical Presentation
TP114 A New Sophisticated GPC/SEC Instrument for High-Throughput and Semi-Micro SECTechnical Presentation
TP127 Characterization of Linear-type SEC Semi-micro Columns for Polymer AnalysisTechnical Presentation
TP128 High-throughput and robust SEC measurement using newly developed all-in-one SEC instrument for polymersTechnical Presentation
TP140 TSKgel High Resolution Size Exclusion Chromatography Column Technology for Organo-Soluble PolymersTechnical Presentation
TP173 Repeatability, Reproducibility, and Baseline Stability of a Dual-Flow Differential Refractive Index Detector for Calculation of Molar Mass Averages in Size Exclusion ChromatographyTechnical Presentation
TP177 Increased Precision in Polymer Analysis via Single-Detector Size Exclusion ChromatographyTechnical Presentation
TP182 Gel Permeation Chromatography Coupled to a Dual Flow Refractive Index Detector for Precise Molar Mass Determination of PolymersTechnical Presentation
TP186 Single Detector Gel Permeation Chromatography for Precise Molar Mass Determination of Polymers in Multiple SolventsTechnical Presentation
TP189 Addressing the Challenges: Improving Polymer Characterization by Size Exclusion Chromatography Technical Presentation
P/NDescriptionParticle Size Housing MaterialID (mm)Length (cm)Price ($) 
0021489TSKgel SuperMPHZ-M Guard4Stainless Steel4.621058